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TA: Formal analysis, Writing review & editing

As a promising material system for high-performance SWIR photodetectors, the I-X-VI chalcogenides - corresponding to the ABC 2 configuration [A = alkali metals (Li, Na, K, Rb, Cs), B = all main group and transition metal elements, C = chalcogen elements (S, Se, Te)] - integrate intrinsic advantages that address core photodetection requirements: strong covalent bonding, tunable direct bandgaps (modulated via ordered-disorder transitions or structural distortion to match the SWIR range, as verified in AgBiS 2 [28] and CuTlSe 2 [29] ), excellent p-type dopability, and robust mechanical/thermodynamic stability (confirmed by first-principles calculations [30] )

S South Yorkshire Hospitals Research Collaboration

EPR finalizes structure interpretation